SYNTHESIS AND PROPERTIES OF AZO COMPOUNDS BASED ON SOME AROMATIC AMINES WITH β-NAPHTHOL
Authors
Saparbayev Suroj Rustamovich, Yuldasheva Muhabbat Razzoqberdievna

Share
Annotation
In this article, the synthesis of azo compounds with β-naphthol based on aromatic amines with p-substituents was studied. The reaction conditions, physicochemical properties of azo compounds and the structure of the resulting products were determined by spectroscopic methods. Based on the results obtained, the effect of substituents on the product yields was studied. The relevance of the topic is that complexes of the obtained azo compounds with metals (Ni2+, Cu2+) were obtained. The following azo dyes combine with metals to form bidentates.
Keywords
Authors
Saparbayev Suroj Rustamovich, Yuldasheva Muhabbat Razzoqberdievna

Share
References:
Al-Tohamy R. et al. A critical review of dye wastewater treatment: ecotoxicological and health issues of textile dyes and possible approaches to restore environmental safety // Ecotoxicology and Environmental Safety. – 2022. – T. 231. – B. 113160.
Alsantali R. I. et al. Various azo dyes: a comprehensive review of recent advances in biological and industrial applications // Dyes and Pigments. – 2022. – T. 199. – B. 110050.
Smith,J.G.Organic Chemistry, 6th ed.;McGraw-Hill Education, 2019]
Al-Rubaie L. A. A. R., Mhessn R. J. Synthesis and characterization of azo dye para red and new derivatives //Journal of Chemistry. – 2012. – T. 9. – No. 1. – S. 465-470.
Jarad A. J., Majeed I. Y., Hussein A. O. Synthesis and spectral studies of heterocyclic azo dye complexes with some transition metals //Journal of Physics: Conference Series. - IOP Publishing, 2018. - T. 1003. – no. 1. – S. 012021.].
Zhao R. et al. One step synthesis of azo compounds from nitroaromatics and anilines //Tetrahedron letters. - 2011. - T. 52. - no. 29. - S. 3805-3809.
Kohl M. et al. New Azo dyes-based Mg complex pigments for optimizing the anti-corrosion efficiency of Zinc-pigmented epoxy ester organic coatings //Coatings. - 2023. - T. 13. – no. 7. - S. 1276
El‐Wakiel N. A. Synthesis and characterization of azo sulfaguanidine complexes and their application for corrosion inhibition of silicate glass //Applied Organometallic Chemistry. - 2016. - T. 30. – no. 8. - S. 664-673
Raja P. B. et al. Reviews on corrosion inhibitors: a short view // Chemical Engineering Communications. - 2016. - T. 203. - no. 9. - S. 1145-1156
Valiulin R. Organic Chemistry: 100 Must-Know Mechanisms // Organic Chemistry: 100 Must-Know Mechanisms. - De Gruyter, - 2020. - P. 97-98.
Zhang Y. et al. An environmentally friendly approach to the green synthesis of azo dyes with aryltriazenes via ionic liquid promoted CN bonds formation //Dyes and Pigments. - 2018. - T. 158. - S. 438-444
Gür M., Kocaokutgen H., Taş M. Synthesis, spectral, and thermal characterizations of some azo-ester derivatives containing a 4-acryloyloxy group //Dyes and Pigments. - 2007. - T. 72. - no. 1. – S. 101-108
El-Ghamry H. A. et al. A series of nanosized Cu (II) complexes based on sulfonamide azo dye ligands: an insight into complex molecular structures, antimicrobial, antitumor and catalytic performance for oxidative dimerization of 2-aminophenol //Applied Organometallic Chemistry. - 2023. - T. 37. – no. 2. - S. e6978
Ferreira G. R. et al. Supramolecular compounds of azo dyes derived from 1-phenylazo-2-naphthol and their nickel and copper complexes //Supramolecular Chemistry. - 2015. - T. 27. – no. 1-2. - S. 13-20.
Dinchalp H. et al. New thiophene-based azo ligands containing azo methine group in the main chain for the determination of copper (II) ions //Dyes and Pigments. - 2007. - T. 75. – no. 1. – S. 11-24.
Almáši M., Vilkova M., Bednarčík J. Synthesis, characterization and spectral properties of novel azo-azomethine-tetracarboxylic Schiff base ligand and its Co (II), Ni (II), Cu (II) and Pd (II) complexes //Inorganica Chimica Acta. - 2021. - T. 515. - S. 120064.
Abd El-Lateef H. M. et al. Design, synthesis of new mixed azo-hydroxyquinoline complexes; in vitro anti-inflammatory, antifungal, antibacterial, theoretical, and molecular docking interactions Investigation //Journal of Molecular Structure. - 2024. - T. 1307. - S. 138016
Kasare M. S. et al. In-vitro antibacterial activity of Ni (II), Cu (II), and Zn (II) complexes incorporating new azo-azomethine ligand possessing excellent antioxidant, anti-inflammatory activity and protective effect of free radicals against plasmid DNA //Synthetic Communications. - 2019. - T. 49. – no. 23. - S. 3311-3323.
