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SYNTHESIS OF ORGANOSILICINE OLIGOMER BASED ON SODIUM SILICATE

Authors

Eshmurodov Khurshid Esanberdievich, Turaev Khayit Khudaynazarovich, Djalilov Abdulakhat Turapovich, Ashurova Muborak Sherali qizi, Xodjayev Akbarali Akhmеdovich

Rubric:Chemistry
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Annotation

In this work, a study was conducted on the synthesis of high molecular weight organosilicon oligomers such as oligoethylsiloxane based on 1,2-dichloroethane and sodium metasilicate. The synthesis was carried out via a three-step nucleophilic displacement and condensation reaction in the presence of ethylene glycol, in a dimethylsulfoxide (DMSO) solvent, and in an autoclave using potassium hydroxide as a catalyst. The structure of the resulting oligomer was confirmed by FTIR analysis, and its thermal stability was determined by TGA/DTA. The resulting oligomer has hydrophobic properties and can be used in the separation of oil-water mixtures and in the biomedical field.

Keywords

2-dichloroethane
sodium silicate
ethylene glycol
organosilicon oligomer
oligoethylsiloxane
nucleophilic substitution
condensation reaction
dimethylsulfoxide (DMSO)
potassium hydroxide (KOH)
autoclave synthesis
thermal stability
hydrophobicity
FTIR spectroscopy
TGA/DTA
environmental safety
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Authors

Eshmurodov Khurshid Esanberdievich, Turaev Khayit Khudaynazarovich, Djalilov Abdulakhat Turapovich, Ashurova Muborak Sherali qizi, Xodjayev Akbarali Akhmеdovich

References:

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Eshmurodov X.E., Turayev X.X., Djalilov A.T., Geldiyev Yu.A., Babamuratov B.E. Development of carbamide-formaldehyde resin-based glue compositions modified with silicon organic compounds // Austrian Journal of Technical and Natural Sciences. 2020. #7-8.

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