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ADSORPTION PROPERTIES OF AMMONIA MOLECULES ON DIACETATECELLULOSE–SILICA HYBRID BIONANOCOMPOSITE

Authors

Akhror Yarkulov, Jayhun Mamatov, Sardor Otajonov, Davron Kuronboev, Khamdam Akbarov

Rubric:Chemistry
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In this study, the adsorption isotherm of ammonia molecules on diacetatecellulose (DAC)–silica hybrid bionanocomposite at 303 K was described from the initial stage to saturation using the three-term TVFM equation. The adsorption thermokinetics indicated that the equilibrium time for the initial adsorption of ammonia molecules was 6.5 hours, and the differential heat of adsorption was 38.7 kJ/mol. The differential molar entropy curve showed that up to an ammonia amount of 1 mmol/g, the mobility of molecules on the adsorbent surface was high, whereas beyond 1 mmol/g, the ammonia molecules were found to be firmly anchored to the adsorbent.

Keywords

ammonia
adsorption
silica
isotherm
diacetatecellulose
differential heat and entropy.

Authors

Akhror Yarkulov, Jayhun Mamatov, Sardor Otajonov, Davron Kuronboev, Khamdam Akbarov

References:

Amanda M.B. Furtado,Yu Wang, M. Douglas LeVan. Carbon silica composites for sulfur dioxide and ammonia adsorption// J. Microporous and Mesoporous Materials. Volume 165(1) 2013, P. 48-54.

Musawenkosi G Shange, Nduduzo L Khumalo, Samson M Mohomane, Tshwafo E Motaung (2024) Factors Affecting Silica/Cellulose Nanocomposite Prepared via the Sol–Gel Technique: A Review// J. Materials 2024, 17(9), 1937. P.1-23. 

Inês Portugal, Vânia M. Dias, Rui F. Duarte, Dmitry V. Evtuguin. Hydration of Cellulose-Silica Hybrids Assessed by Sorption Isotherms// J. Phys. Chem. B. 2010. V.114(11) P. 4047-4055.

Vitaly Kocherbitov, Stefan Ulvenlund, Maria Kober, Kjell Jarring, and Thomas Arnebrant. Hydration of Microcrystalline Cellulose and Milled Cellulose Studied by Sorption Calorimetry // The Journal of Physical Chemistry B, 2008, 112(12), P. 3728–3734. 

Ahmed Salama. Polysaccharides-silica hybrid materials: New perspectives for sustainable raw materials // Journal of Carbohydrate Chemistry. 2016. V.35(3). -P. 131-149.

Hua Zou, Shishan Wu, Jian Shen. Polymer/Silica Nanocomposites: Preparation, Characterization, Properties, and Applications // Chemical Reviews. -2008. -V.108(9). -P. 3893-957.

Sadanand Pandey, Shivani B. Mishra. Sol-gel derived organic-inorganic hybrid materials: Synthesis, characterizations and applications // Journal of Sol-Gel Science and Technology. -2011. -V.59(1). -P.73-94.

A. Yarkulov, B. Umarov, F. Rakhmatkarieva, N. Kattaev, Kh. Akbarov, E. Berdimurodov. Diacetate Cellulose-Silicon Bionanocomposite Adsorbent for recovery of Heavy Metal ions and Benzene Vapours: An Experimental and Theoretical Investigation// Biointerface Research in Applied Chemistry- Open-Access Journal (ISSN: 2069-5837). –2022, –V. 12(3), –P. 2862-2880.

Akhror Yarkulov, Mirazim Sobitov, Bakhrom Umarov, Feruza Rakhmatkarieva, Bakhtiyor Sagdullaev, Khamdam Akbarov. Thermodimics of adsorbtion of heptane molecules by hybrid bionanocomposite diacetatecellulose-silica. Problems in the Textile and Light Industry in the Context of Integration of Science and Industry and Ways to Solve Them AIP Conf. Proc. 3045, 030062-1–030062-6.

A.Y. Shining Adsorption of n-heptan molecule to hybrid diatsetacellyuloza-kremnezem bionanokompositionsiga. O`zMU khabalari. Tashkent. 2024 3/1 son. B. 475-479.

Y. Yakubov, G. Rakhmatkariev, F. Rakhmatkarieva. Adsorption energetics of gases in H3,25ZSM-5 zeolite// Austrian Journal of Technical and Natural Sciences. Vienna (Austria). 2016. No. 5-6. –PP. 79-83.

Yarkulov A.Yu., Sagdullaev B.U., Akbarov H.I. Thermodynamics of molecular adsorption of n-heptane by hybrid bionanocomposite diacetate cellulose-silica // Universum: chemistry and biology: electron. science journal 2024. 1(115). URL: https://7universum. com/ru/nature/archive/item/16610. P. 46-50.

A.Yu. Yarkulov. Thermodynamic properties of hybrid cellulose diacetate silica nanocomposites. SamSU Scientific Bulletin. Samarkand 2020. Issue 3 (121) – P. 50-54.

Abdurakhmonov Eldor Baratovich, Rakhmatkarieva Firuza Gayratovna, Ergashev Oybek Karimovich Determination of ammonia’s adsorption properties in NaLSX zeolite by calorimetric method // "International Journal of Materials and Chemistry" Vol. 10 No. 2, 2020, P. 17-22.

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