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SELECTION OF HIGHLY ACTIVE MATERIAL FOR SEMICONDUCTOR SENSORS OF CARBON MONOXIDE, HYDROGEN AND HYDROCARBONS BASED ON INDIVIDUAL METAL OXIDES.

Authors

Mavjuda Eshkobilova, Zulaikho Smanova, Abdurakhmanov Ergashboy

Rubric:Chemistry
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In this work, we investigated the catalytic activity of individual metal oxides (CuO, MnO₂, SnO₂, Cr₂O₃, Co₂O₃, ZrO₂, TiO₂, etc.) in the oxidation of carbon monoxide (CO), hydrogen (H₂), and hydrocarbons (methane, n-octane) in order to select the optimal material for semiconductor gas sensors. Experiments were conducted using gas-air mixtures at a controlled temperature of 350 °C and a fixed flow rate. The activity and selectivity of the oxides, as well as their dependence on physical properties, such as the metal–oxygen bond length and band gap, were determined. The results show that CuO, MnO₂, and SnO₂ are the most active oxides for CO oxidation, and ZrO₂ is the most active for the selective detection of H₂. These findings enable the creation of semiconductor sensors with improved operational and metrological characteristics.

Keywords

metal oxides
semiconductor sensor
carbon monoxide
hydrocarbons
hydrogen
catalytic activity
selectivity.

Authors

Mavjuda Eshkobilova, Zulaikho Smanova, Abdurakhmanov Ergashboy

References:

Kh G Sidikova E Abdurakhmanov, ZB Murodova, ME Eshkobilova//Development of a selective sensor for the determination of hydrogen//IOP Conference Series: Earth and Environmental Science// doi:10.1088/1755-1315/839/4/042086

Sh.Pardaeva E.Abdurakhmanov M Eshkabilova, N Muminova , Kh Sidikova//Template Synthesis of Nanomaterials based on Titanium and Cadmium Oxides by the Sol-Gel Method, Study of their Possibility of Application As A Carbon Monoxide Sensor (II)//Journal of Pharmaceutical Negative Results ¦ Volume 13 ¦ Special Issue 3 ¦ 2022//DOI: 10.47750/pnr.2022.13.S03.210//1343-1350

E Abdurakhmanov and Z Abdurakhmanova. M Eshkabilova, I E Abdurakhmanov, Z Muradova//Development of selective gas sensors using nanomaterials obtained by sol-gel process//Journal of Physics: Conference Series, : Journal of Physics: Conf. Series, IOP Conf. Series: Journal of Physics: Conf. Series5//https://iopscience.iop//.org/article/10.1088/1742-6596/2388/1/012155

Abdurakhmanov E. Eshkobilov Sh. A., Eshkobilova M. E. // Development of a catalyst for a sensitive natural gas sensor // International scientific journal "Symbol of Science". // P. 7-11 2015

ME Eshkobilova, N Хodieva, ZE Abdurakhmanova//Thermocatalytic and Semiconductor Sensors for Monitoring Gas Mixtures//  World Journal of Agriculture and Urbanization//2023/6/17//C 9-13

Nasimov A. M. Eshkobilova M. E. // Gas analyzer (TPG-CH4) for methane monitoring based on thermocatalytic and semiconductor sensors // Journal "Universum: Chemistry and Biology" No. 6 (60). DOI: 10.32743/UniChem.2019.60.6

Abdurakhmanov Ergashboy Eshkobilova Mavjuda//Zol-gel synthesis of nanocomposites and gaseous materials//The International Conference on “Energy-Earth-Environment-Engineering”//2023/12//C 84-85.

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