Synthesis of [Co(bpy)(SCN)4]2+ complex and its photochemical properties in the sol-gel matrix

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Synthesis of [Co(bpy)(SCN)4]2+ complex and its photochemical properties in the sol-gel matrix

Authors

Toshpulatov D.T., Mirzaev Sh.E., Nasimov A.M., Yakubov B.A., Samiev A.A., Tashpulatov Kh.Sh.

Rubric:Chemistry
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Synthesis of [Co(bpy)(SCN)4]2+  complex carried and its photochemical  properties studies explored in both organic solvent and tetraethoxysilane based sol-gel membrane. TEOS based sol-gel membrane shown suitable matrix and cobalt dye retain its photochemical properties inside the pores of membrane.  Based on spectral changes in the sol-gel ma matrix, possible changes in molecular shape also discussed. Moreover, the sol-gel membrane confirm cobalt complex from photobleaching or degradation.   

Keywords

complex
sol-gel matrix
TEOS
absorption
immobilization
MLCT band.

Authors

Toshpulatov D.T., Mirzaev Sh.E., Nasimov A.M., Yakubov B.A., Samiev A.A., Tashpulatov Kh.Sh.

References:

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