In the original languageTranslation into English
SYNTHESES AND TECHNOLOGY OF 2-BROMO-SUBSTITUTED BIS-CARBAMATE DERIVATIVES, PROPERTIES AND THEIR APPLICATION
Authors
Ziyadullayev A.E, Kholikulov B.N, Makhsumov A.G, Umrzokov A. T
Rubric:Chemistry
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Annotation
The article studied the synthesis of N,Nʹ-hexamethylenebis[(2-bromophenoxy)-carbamate], The products of N,Nʹ-dichloro substitution, N , N'-dinitroso substitution, N,N'-disodium substitution and N,N'-dibenzyl substitution were studied N,Nʹ-hexamethylenebis[(2-bromophenoxycarbamate] formed during the synthesis. Reaction centers and the reaction mechanism involved in the synthesis of these substances have also been proposed. proved by IR spectroscopy.The process used organic solvents and catalysts.The reaction yield was from 90.6% to 93.3%.The biological activity of the obtained substances was studied and compared with the Roslin preparation.
Keywords
2-bromo-substituted bis-carbamates
N
N'-hexamethylenebis[(2-bromophenoxy)-carbamate]
N'-dichloride
N'-dinitroso
N'-disodium
N'-dibenzyl.
Authors
Ziyadullayev A.E, Kholikulov B.N, Makhsumov A.G, Umrzokov A. T
Rubric:Chemistry
521
3
Share
521
3
References:
- MakhsumovAG, Atakhodzhaeva M.A. Synthesis and antimicrobialactivity of bromine- PE pyrazolyl-M-methylcarbamate // Chemical Pharmaceutical Journal, Moscow, №4, 1988. P. 431-433.
- Sutoris V., Sunak J., Cipinova H. Preparation of ethinyl esters and carbamates and the study of their pesticidal action// Chem.J.Vesti, 23, No. 11, 1969, P.47-48.
- Melnikov N.N., Baskanov Yu.A. Synthesis and physiological activity on plants of isopropyl ethers of some arylcarbamic acids //J. General Chemistry, No. 24, 1954, p. 376-379.
- Karmanova L.P., Kuchin A.V., Koroleva A.A. Chemistry, technology of bioregulators // 17th Mendeleev Congress on General and Applied Chemistry, Kazan, Russian Federation, 2003. P.243.MOSZYNSKI Wieslaw. The pesticidal activity of aryl esters of N-arylcarbamic acid // Organga.Ponaik.Ingot.Organ.. 1980. P.53-58.
- Makhsumov A.G., Samadov S.Zh., Nazirov Z.Sh. The production technology of the bis derivative - [(ortho-aminoacetylphenoxy) - carbamate] and its properties // Chemical Journal of Kazakhstan, Almaty, No. 2, 2008, P.163-170.
- Makhsumov A.G., Atakhodzhaeva М.А., Talipova М.А., Djuraev A.D. Synthesis and study of PYA pyrazolyl N-methylcarbamates // Chemical- Pharmaceutical Journal. Moscow, No. 4.1988, p. 431-433.
- Makhsumov A.G., Zakirov U.B., Atakhodzhaeva М.A. Study of the pharmacological properties of propargilcarbamate derivatives // J. Physiol, active substances, Kiev, Ukraine, Vol. 13, 1981. P.50-52.
- Patent 7074782 United States / Carbamate in case of caspase and their application // Beblington David, Knegtel Ronald, Mortimore Michael // IPS7, from 07 D 213/8; it is declared on Avgust 21,2003; Published on; July 11. 2006.
- Khatamova M.S., Makhsumov A.G. Moderm achievements in the synthesis of bis (alkyl) -carbamate derivatives and their propirties // Semical Journal of Kazakhstan, Special issue - Almaty, 2007, R. 120-124.
- Siddikova Kh.H.. Makhsumov AG. Isaev AN. “NauchnyVestnik”, And.State University, 2017, No. 4, P .22-25.
- Makhsumov A.G., Nabiev V.A., Valeeva N.G.. Development of synthsis, properties of derivative 1-aminoantrauchinon and its bio-simulating activity //Monthly International scientific Journal "Austria-science" 2018, I part, №16, P.65-70.
- BarkanYa.G. Organic chemistry//Moscow, "Higher Schaol", 1973, P.471.BarkanYa.G. Organic chemistry // Moscow, "Higher Schaol", 1973, P.471.
- Makhsumov A.G., Ismatov D.N., Valeeva N.G. Synthesis, properties andbiologicalactivity N,N'gexamethlene bis-[(l-naphtoxy)-carbamate]. International journal of Engineering sciences and research technology, 2018, 7(8), P. 194- 200.
- Makhsumov A.G., Absalyamova Q.M., Ismailov B.M., Mashayev E.E. Synthesis and properties of the derivative-N, N1-hexamethylene bis - [(ortho- aminoacetylphenoxy)] - carbamate and its application // ’’UNIVERSIM: CHEMISTRY AND BIOLOGY. Moscow. 2019, No. 3, P. 65-71.
- Makhsumov A.G., Samadov S.J., Valeeva N.G. Synthesis and properties of the derivative-N. N-fetramethylene bis- (h-ferrocenylhenoxy) - carbamate and its application // International Journal of Engineering and Scientific Research, (Indiya). 2019. Vol.7 Issue 2, Month, p. 1 -7.
- Makhsumov A.G. Synthesis, , properties and biological activity of L-borneola carbamate derivative // International Journal of Engineering and Scientific Research, (Indiya). 2019, Vol.7 Issue 1,January, p. 1-8.
- Makhsumov A.G.,Ismatov D.N., Valeeva N.G., Asadova R.D., Ruzmatov b. Modern advances in the synthesis of new derivatives of acetylene dithicarbamate and theis biological activity // International Journal of Engineering and Scientific Research, (Indiya). 2019, Vol.7 Issue 3,March, p. 1-9.
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