The Influence of Certain Functional Groups on Adsorption Processes and Micelle Formation in Aqueous Solutions of Surfactants
Authors
Maslak Hanna Sergiivna, Maryaskin Yuri Borisovich, Stanislav Derman, Netronina O.
![](/api/crop/media/uploads/journals/journal/ESR_24_KbmPseM.jpg?geometry=280x368)
Share
Annotation
I am writing to submit our manuscript entitled "The Influence of Certain Functional Groups on Adsorption Processes and Micelle Formation in Aqueous Solutions of Surfactants" for consideration in Journal of Colloid And Interface Science. This work presents a detailed study on the thermodynamic interactions within surfactant solutions, particularly focusing on the role of functional groups in adsorption processes and micelle formation. Our research provides new insights into the thermodynamic properties of surfactant aqueous solutions, guided by an analytical approach that dissects the contributions of hydrophobic and hydrophilic groups to the overall Gibbs free energy changes during micelle formation and adsorption. By integrating theoretical analyses with empirical data, our study extends the foundational work referenced in seminal texts and recent studies, thus contributing substantial advancements to the field of colloidal and surface chemistry. The manuscript details how the hydrophobic interactions primarily drive micelle formation, revealing a linear dependency of Gibbs free energy changes on the number of hydrocarbon groups in the surfactant molecules. Furthermore, we explore the selective inclusion of hydrophilic groups in micelles and establish the comparative thermodynamic favorability of adsorption processes over micelle formation, thereby addressing critical aspects of surfactant behavior in solution that influence their technological applications. Given the scope and the rigorous analytical framework of our study, we believe that the findings presented would be of significant interest to the readership of [Journal Name], particularly those involved in research or application of surface-active agents in various industrial and scientific contexts. Please find attached the manuscript for your review. We appreciate your consideration of our work for publication and eagerly await your positive response. Should you require any further information or modifications to the manuscript, please do not hesitate to contact me at. Thank you for considering our submission.
Keywords
Authors
Maslak Hanna Sergiivna, Maryaskin Yuri Borisovich, Stanislav Derman, Netronina O.
![](/api/crop/media/uploads/journals/journal/ESR_24_KbmPseM.jpg?geometry=280x368)
Share
References:
Lin I.J., Marszall L. "Partition of HLB Coefficient and Effective Chain Length of Surface-Active Agents." Progress in Colloid and Polymer Science, vol. 63, 1978, pp. 99–104.
Maryaskin Y., Derman S. "Relation of Surface-Active Agents Solutions Surface and Volume Properties." European Science Review, vol. 1, no. 11-12, 2019, pp. 136–140.
Lin I.J. "The Hydrophile-Lipophile Balance (HLB) of Fluorocarbon Surfactants and Its Relation to the Critical Micelle Concentration (CMC)." The Journal of Physical Chemistry, vol. 76, no. 14, 1972, pp. 2019–2023.
Maryaskin, Y.B., Danilov, F.I. "The Relationship Between Colloidal-Chemical Properties and the Hydrophilic-Lipophilic Balance of Surface-Active Substances." Questions of Chemistry and Chemical Technology, no. 3, 2004, pp. 136–140.
Maslak, H.S., Maryaskin, Y.B., Derman, S. "Influence of Micellar Structures on the Adsorption Capacity of Surfactants." European Science Review, no. 9–10, 2023.
Israelachvili, J.N. "Intermolecular and Surface Forces." Academic Press, 2011.
Rosen, M.J., Kunjappu, J.T. "Surfactants and Interfacial Phenomena." Wiley, 2012.
Myers, D. "Surfactant Science and Technology." Wiley-VCH, 2005.
Volkov, V.A. "The Influence of Molecular Structure on Micelle Formation in Solutions of Surface-Active Substances." Colloid Journal, vol. XXXVII, no. 5, 1975, pp. 845–852.