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Investigation of the Sorption Properties of Sapropel in Industrial Wastewater

Authors

Gulnoza Zayniddin qizi Khomitova, Matluba Mukhtarovna Amonova

Rubric:Chemistry
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This article investigates the treatment of textile and printing industry wastewater using a sorbent based on local sapropel. The aim was to evaluate stabilization of the cation-anion composition and the deep purification of highly mineralized wastewater contaminated with organic dyes generated during the washing of printed fabrics. Physicochemical analysis showed that the initial wastewater contained 608 mg/L sulfate and had a total hardness of 14.4 meq/L; it was also characterized by a reddish color and a sulfurous odor associated with 32.3 mg/L hydrogen sulfide. Treatment with the sapropel-based sorbent reduced sodium from 215 to 105 mg/L, sulfate from 608 to 298 mg/L, total hardness to 7.78 meq/L, and hydrogen sulfide to 14.23 mg/L. Decolorization and deodorization were also achieved. The results demonstrate the sorption potential of humic and mineral components of sapropel and support further development of this local material for industrial wastewater treatment. Because ammonium, nitrate, and oxidizability did not decrease, an additional polishing stage should be evaluated when deeper removal of nitrogenous and oxidizable contaminants is required.

Keywords

total hardness
composite sorbent
ion-exchange adsorption
demineralization
sulfate removal
sorption activity
wastewater
environmental safety.
humic acid
modified sapropel

Authors

Gulnoza Zayniddin qizi Khomitova, Matluba Mukhtarovna Amonova

 

References:

Adeeva, L. N., & Kovalenko, T. A. (2012). Removal of organic substances and metal ions from water using a carbon-mineral sapropel sorbent. Russian Journal of Applied Chemistry, 85, 557-563. https://doi.org/10.1134/S1070427212040040

Adeeva, L. N., Platonova, D. S., Puzhel, A. V., Didenko, T. A., & Belykh, N. A. (2013a). Bifunctional sorbent for wastewater treatment obtained from sapropel. Butlerov Communications, 34(6), 70-75. (In Russian). ROI: jbc-01/13-34-6-70

Adeeva, L. N., Platonova, D. S., Masorov, M. S., & Didenko, T. A. (2013b). Humic acids from siliceous sapropel: IR-spectroscopic and thermal analysis. Butlerov Communications, 34(6), 65-69. (In Russian). ROI: jbc-01/13-34-6-65

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Chechevatov, A. I., Miroshnichenko, Y. S., Myasoedova, T. N., Popov, Y. V., & Yalovega, G. E. (2017). Investigations of the capability of humic acids to adsorb heavy metals: Correlation between structure and absorption properties. In Advanced Materials: Techniques, Physics, Mechanics and Applications (pp. 99-110). Springer. https://doi.org/10.1007/978-3-319-56062-5_9

Kovalenko, T. A., & Adeeva, L. N. (2010). Carbon-mineral sorbent from sapropel for comprehensive wastewater treatment. Chemistry for Sustainable Development, 18(2), 189-195. (In Russian).

Platonova, D. S., & Adeeva, L. N. (2018). Use of humic sorbent from sapropel for extraction of palladium ions from chloride solutions. Open Engineering, 8(1), 176-181. https://doi.org/10.1515/eng-2018-0023

Platonova, D. S., Gurin, A. V., & Adeeva, L. N. (2016). Modified sorbents of sapropel for wastewater treatment. Ecology and Industry of Russia, 20(11), 20-25. https://doi.org/10.18412/1816-0395-2016-11-20-25

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