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Electrochemical Treatment of Industrial Wastewater: A Comprehensive Analytical Review and Conceptual Evaluation

Authors

Vladyslav Meleshko

Rubric:Technical sciences in general
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The article presents a novel electrochemical technology for wastewater treatment based on volumetric permeable electrodes operating in a flow-through regime. The proposed system enables controlled modification of water properties, including pH adjustment and microbial inactivation.

The study introduces a modular reactor design based on chemically stable materials and highlights the integration of non-contact monitoring systems using electromagnetic resonance spectroscopy. The approach is evaluated in the context of modern electrochemical water treatment methods, including advanced oxidation processes and hybrid systems (Brillas & Garcia-Segura, 2025; Ganiyu et al., 2020).

The technology is presented as a cost-effective and scalable alternative to existing electrochemical treatment methods.

Keywords

electrochemical wastewater treatment
volumetric electrochemical reactors
permeable electrodes
flow-through systems
three-dimensional (3D) electrodes
advanced oxidation processes (EAOPs)
electro-Fenton
reactive electrochemical membranes (REM)
non-contact sensing
electromagnetic resonance spectroscopy
real-time monitoring
sustainable water treatment
decentralized water systems
modular reactor design.

Authors

Vladyslav Meleshko

Rubric:Technical sciences in general
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References:

Meleshko, V. (2026). Electrochemical Treatment of Industrial Wastewater. Published online at IntellectualArchive.com, March 4, 2026.

Brillas, E., & Garcia-Segura, S. (2025). Electrochemical advanced oxidation processes for real wastewater remediation: Systems, performance, and generated oxidants. ACS Electrochemistry, 2(1), 45–68. https://doi.org/10.1021/acselectrochem.5c00311.

Oturan, M. A., & Aaron, J.-J. (2014). Advanced oxidation processes in water/wastewater treatment: Principles and applications. A review. Critical Reviews in Environmental Science and Technology, 44(23), 2577–2641. https://doi.org/10.1080/10643389.2013.829765.

Heidari, Z., Pelalak, R., & Zhou, M. (2023). Recent progress in electro-Fenton process for wastewater treatment at near-neutral pH: A review. Chemical Engineering Journal, 468, 143600. https://doi.org/10.1016/j.cej.2023.143600.

Li, X., Zhang, Y., Wang, H., & Chen, G. (2025). Advances in heterogeneous electro-Fenton processes for efficient water treatment. Journal of Hazardous Materials, 465, 133210. https://doi.org/10.1016/j.jhazmat.2024.133210.

Du, M., Li, W., Zhang, D., & Chen, Z. (2025). Recent advances in electrochemical membrane reactors based on cathodic carbon membranes for water treatment. Journal of Membrane Science, 712, 121345. https://doi.org/10.1016/j.memsci.2024.121345.

Zhu, Y., Wang, L., & Chen, Z. (2023). Electrochemical anodic oxidation-based membrane systems for micropollutant removal. ACS ES&T Engineering, 3(4), 1123–1137. https://doi.org/10.1021/acsestengg.3c00179

Dong, T., Li, J., & Wang, S. (2025). Recent advances in oxidant-involved photoelectrochemical systems for sustainable wastewater treatment. Nature Reviews Clean Technology, 1, 45–67. https://doi.org/10.1038/s44296-025-00084-6.

Amaya Santos, G., Martínez-Huitle, C. A., & Rodrigo, M. A. (2025). Scaling-up photoelectrochemical oxidation processes: From laboratory to industrial applications. Water Research, 248, 120715. https://doi.org/10.1016/j.watres.2025.120715.

Martínez-Huitle, C. A., & Brillas, E. (2009). Decontamination of wastewaters containing synthetic organic dyes by electrochemical methods: A general review. Applied Catalysis B: Environmental, 87(3–4), 105–145. https://doi.org/10.1016/j.apcatb.2008.09.017.

Panizza, M., & Cerisola, G. (2009). Direct and mediated anodic oxidation of organic pollutants. Chemical Reviews, 109(12), 6541–6569. https://doi.org/10.1021/cr9001319.

Rodrigo, M. A., Oturan, N., & Oturan, M. A. (2014). Electrochemically assisted remediation of pesticides in soils and water: A review. Chemical Reviews, 114(17), 8720–8745. https://doi.org/10.1021/cr5002059.

Ganiyu, S. O., Martínez-Huitle, C. A., & Oturan, M. A. (2020). Electrochemical advanced oxidation processes for wastewater treatment: Advances in formation and detection of reactive species and mechanisms. Current Opinion in Electrochemistry, 22, 57–64. https://doi.org/10.1016/j.coelec.2020.04.002.

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