SYNTHESIS OF MIXED-LIGAND COMPLEX COMPOUNDS BASED ON MANGANESE(II) METAGYDROXIBENZOATE AND NICOTINAMIDE AND STUDY OF THE CORRELATIONS BETWEEN THEIR COMPOSITION AND STRUCTURE
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Kurbanova Rakhila Salievna, Khasanov Shodlik Bekpulatovich, Abdullaeva Zubayda Shavkatovna
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In this article, the synthesis, structure, and physicochemical properties of complex compounds formed with nicotinamide in the presence of the divalent manganese ion were studied in detail. m-Hydroxybenzoic acid was used as the primary ligand. The elemental analysis method was employed to determine the composition of the synthesized complex compounds. The optimized geometric structure, molecular electrostatic potential (MEP), frontier molecular orbitals (HOMO–LUMO), and global chemical reactivity parameters were analyzed based on density functional theory (DFT) quantum chemical calculations.
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Authors
Kurbanova Rakhila Salievna, Khasanov Shodlik Bekpulatovich, Abdullaeva Zubayda Shavkatovna
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References:
Beppu, M., et al. (2019). Drug delivery using phenolic acid–based polymeric carriers. Biomaterials Science, 7(9), 3697–3705. Retrieved from https://doi 10.1039/C9BM00540D
Christou, G. (2005). Single-molecule magnets: a molecular approach to nanoscale magnetic materials. Polyhedron, 24, 2065–2075. Retrieved from https://doi.org/10.1016/j.poly.2005.08.010
Juyal, V., Thakuri, S. C., Panwar, M., Rashmi, O., Bukhari, N. A., & Nand, V. (2024). Manganese(II) and zinc(II) metal complexes of novel bidentate formamide-based Schiff base ligand: Synthesis, structural characterization, antioxidant, antibacterial, and in-silico molecular docking study. Frontiers in Chemistry – Inorganic Chemistry. Retrieved from: https://doi.org/10.3389/fchem.2024.1414646
Karakaya, S., & El, S. N. (2018). Phenolic Acid Derivatives Used in Food and Medicine: A Review. Trends in Food Science & Technology, 85, 64–72. Retrieved from:https://doi 10.1016/j.tifs.2018.02.001
Liu, X. F., Ma, N. N., Feng, F., et al. (2020). Syntheses, Crystal Structure, and Magnetic Property of a New Mn(II) Complex with an Aromatic N-heterocyclic Tetracarboxylic Acid Ligand. Russian Journal of Coordination Chemistry, 46, 365–370. Retrieved from: https://doi.org/10.1134/S1070328420050036
Matmurodova, F., Xudoyberganov, O., Hasanov, Sh., & Taxirov, Y. (2023). Synthesis of coordination compound of Mn(II) ion with 2-(diethylamino)ethyl-aminobenzoate. O‘zbekiston milliy universiteti xabarlari, [3/1], 396–399. Retrieved from: https://nuu.uz
Migwi, F. K., Nyamato, G. S., Ojwach, S. O., & Darkwa, J. (2025). A review of the recent coordination chemistry and catalytic applications of pyrazole and pyrazolyl transition metal complexes. Coordination Chemistry Reviews, 450, 214–256 Retrieved from: https://www.sciencedirect.com/science/article/abs/pii/S0010854525009439
Osman, U. M., et al. (2020). Thiosemicarbazide ligand complexes of Ni(II): XRD and spectroscopic studies. Journal of Molecular Structure, 1215, 128–135. Retrieved from: https://www.sciencedirect.com/science/article/pii/S002228602031317X
Salgado, H. R. N. (2020). Hydroxybenzoic acids as potential antimicrobial and anti-inflammatory agents: Mechanisms and applications. Journal of Pharmacy and Pharmacology, 72(6), 773–790. Retrieved from https://doi 10.1111/jphp.13215
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