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STRUCTURE AND PROPERTY RELATIONSHIPS IN OXIDIZED STARCH BASED COMPOSITE WOOD ADHESIVES

Authors

Ortiqov Sherzod Sharof og’li, Radjabov Otabek Iskandarovich, Sharipov Muzafar Samandarovich, Khafizov Alisher Rakhimovich

Rubric:Chemistry
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Annotation

Composite wood adhesives based on oxidized starch were prepared using different formulations, including OS:PAA:PVA, OS:PAA:CA, and OS:PAA:PVA:U systems. The relationship between structure and properties was investigated using scanning electron microscopy (SEM) and thermogravimetric analysis (TG). SEM analysis revealed that the OS:PAA:CA system forms a dense, homogeneous, and compact structure, while the OS:PAA:PVA and OS:PAA:PVA:U systems exhibit more heterogeneous and porous morphologies. Thermogravimetric results showed that all samples undergo three main stages of thermal degradation, with the OS:PAA:CA composition demonstrating the highest thermal stability due to the formation of a well-developed three-dimensional network. The results indicate that the performance of oxidized starch-based adhesives strongly depends on the composition and intermolecular interactions between components. Among the studied systems, the OS:PAA:CA composition exhibited the most favorable structural and thermal properties, making it a promising candidate for wood adhesive applications.

Keywords

oxidized starch; composite adhesives; wood adhesive; SEM analysis; thermal stability; structure–property relationship.

Authors

Ortiqov Sherzod Sharof og’li, Radjabov Otabek Iskandarovich, Sharipov Muzafar Samandarovich, Khafizov Alisher Rakhimovich

References:

Liang, J., Li, D., Luo, Z., Yang, Y., Meng, T., Chen, C., Li, H., Zuo, N., Li, Q., Yang, H., & Wu, Z. (2025). Starch-citric acid adhesive: Preparation and performance study catalyzed by p-toluenesulfonic acid. Polymers, 17(23), Article 3224. https://doi.org/10.3390/polym17233224

Shen, D., Li, X., Liu, Y., Liu, C., Zheng, A., Wang, X., Liu, Y., & Liu, G. (2023). Effects of different molecular weight oxidized dextran as crosslinkers on the structure and properties of composite nanoparticles. Journal of Biomaterials Science, Polymer Edition, 34(14), 1706–1724. https://doi.org/10.1080/09205063.2023.2225620

Palić, N., Gržetić, J., Đolić, M., Kovačević, T., Pecić, Lj., Radovanović, Ž., & Marinković, A. (2020). Preparation and properties of hydrogen peroxide oxidized starch for industrial use. Hemijska industrija, 74(1), 25-36. https://doi.org/10.2298/HEMIND190722004k

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McHugh, T. H., Avena-Bustillos, R., & Krochta, J. M. (1993). Hydrophilic edible films: Modified procedure for water vapor permeability and explanation of thickness effects. Journal of Food Science, 58(4), 899-903. https://doi.org/10.1111/j.1365-2621.1993.tb09387.x

 

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