Synthesis, crystal structure and properties of a new bi-dentate decavanadate [Co(H3SO3)+(H2O)5]2[H2V10O28]·2H2O·2SO3
Authors
Мehribon Pirimova, Malika Yakubxodjayeva, Muparrax Xodjayeva
Share
Annotation
A new bi-dentate decavanadate compound formulated [Co(H3SO3)+(H2O)5]2[H2V10O28]·2H2O·2SO3 (1), has been synthesized under hydrothermal condition by using sulfuric acid as the initiator at 110 °C. And 1 crystallizes in the triclinic, space group P-1 with a = 9.8954(7) Å, b = 10.4827(9) Å, c = 12.8466(7) Å, α = 76.395(6), β = 82.024(6), γ = 68.836(7), V = 1205.7 Å3, R1(I > 2s(I) = 3.61), and Z = 5. X-ray diffraction analysis reveals that 1 is constructed from bi-dentate decavanadate formed by decavanadate clusters coordinated to [Co(H3SO3)+(H2O)5]2+ complexes and free water molecules.
Keywords
Authors
Мehribon Pirimova, Malika Yakubxodjayeva, Muparrax Xodjayeva
Share
References:
Liu, H., Wang, J., Jian, F., & Xiao, H. (2009). Synthesis and crystal structure of two decavanadates cluster metal complexes: [Co(H₂O)₆]₂[H₂V₁₀O₂₈]·6H₂O and (NH₄)₂[Ca(H₂O)₇]₂[V₁₀O₂₈]. Journal of Cluster Science, 20(4), 621–627. https://doi.org/10.1007/s10876-009-0265-2
Msaadi, I., Rayes, A., Benito, M., Issaoui, N., Molins, E., & Ayed, B. (2022). A combined experimental and theoretical study of two new decavanadates: (C₆N₂H₉)₄[H₂V₁₀O₂₈]·4H₂O and (C₇H₉NF)₄[H₂V₁₀O₂₈]·2H₂O. Journal of Molecular Structure, 1262, 133085. https://doi.org/10.1016/j.molstruc.202133085
Pope, M. T., & Müller, A. (2001). Polyoxometalate Chemistry: From Topology via Self-Assembly to Applications. Springer.
Hill, C. L. (1998). Polyoxometalates: Reactivity and catalytic applications. Chemical Reviews, 98(1), 1–390. https://doi.org/10.1021/cr9603980
Sheldrick, G. M. (2015). Crystal structure refinement with SHELXL. Acta Crystallographica Section C: Structural Chemistry, 71(1), 3–8. https://doi.org/10.1107/S2053229614024218
1. Sheldrick, G. M. “Crystal structure refinement with SHELXL.” Acta Crystallographica Section C 71 (2015): 3–8.
2. Pope, M. T., Müller, A. Polyoxometalate Chemistry: From Topology via Self-Assembly to Applications. Springer, 2001.
3. Hill, C. L. “Polyoxometalates: Reactivity and Catalytic Applications.” Chemical Reviews 98, no. 1 (1998): 1–390.
Other articles of the issue
