Academic publishing in Europe and N. America

Archive Publication ethics Submission Payment Contacts
In the original languageTranslation into English

PHYSICOCHEMICAL CHARACTERIZATION OF SERPENTINITE-MODIFIED AMMONIUM NITRATE

Authors

Buriyev Sayfutdin, Namazov Shafoat, Mamataliyev Abdurasul, Kushokov Jamoliddin

Rubric:Chemistry
1239
1
Download articleQuote
1239
1

Annotation

This study investigates the effect of serpentinite as a stabilizing additive to ammonium nitrate (AN) by analyzing its physicochemical properties through XRD, SEM-EDS, and DSC techniques. Serpentinite, rich in magnesium silicates, was added in varying ratios to AN to reduce its thermal sensitivity. The results showed that the addition of serpentinite did not disrupt the crystalline structure of AN, while improving its thermal behavior and particle dispersion. The composition with a 10:2.5 AN to serpentinite ratio exhibited optimal performance, showing delayed decomposition, enhanced thermal stability, and better structural integrity. These findings highlight serpentinite's potential as an effective, low-cost stabilizer for improving the safety of ammonium nitrate-based materials.

Keywords

XRD
SEM-EDS
DSC analysis
Physicochemical properties.
thermal stability
Ammonium nitrate
serpentinite

Authors

Buriyev Sayfutdin, Namazov Shafoat, Mamataliyev Abdurasul, Kushokov Jamoliddin

References:

    1. Abbasi, T., & Abbasi, S. A. (2007). The boiling lake and other stories of excitement: Understanding chemical accidents and disasters. Hyderabad: Universities Press.
    2. Calvert, J. B., & Aylward, G. H. (2003). Thermochemical Processes: Principles and Models. Butterworth-Heinemann.
    3. Conkling, J. A., & Mocella, C. J. (2010). Chemistry of Pyrotechnics: Basic Principles and Theory (2nd ed.). CRC Press.
    4. Mal'tsev, V. N., Zheltov, V. N., & Polovkov, A. V. (2016). Structure and thermal decomposition of ammonium nitrate. Combustion, Explosion, and Shock Waves, 52(1), 48–53. https://doi.org/10.1134/S0010508216010104
    5. Muhammad, N., & Ahmed, I. (2019). Stabilization of ammonium nitrate with nano-additives: A review. Journal of Energetic Materials, 37(2), 140–160. https://doi.org/10.1080/07370652.2018.1540667
    6. Singh, H., Sharma, R., & Raghunathan, R. (2020). Influence of mineral additives on thermal decomposition of ammonium nitrate. Thermochimica Acta, 684, 178484. https://doi.org/10.1016/j.tca.2019.178484
    7. Souri, A., & Dastanpour, R. (2020). Characterization of serpentinite as a raw material in geochemical processes. Applied Clay Science, 191, 105627. https://doi.org/10.1016/j.clay.2020.105627
    8. Venkatesan, S., & Mani, N. (2021). Effect of magnesium silicate minerals on energetic materials. Materials Today: Proceedings, 47(12), 5625–5631. https://doi.org/10.1016/j.matpr.2021.06.379
    9. Wang, L., Zhang, Q., & Yu, X. (2022). DSC and TG analysis of ammonium nitrate and its composites. Journal of Thermal Analysis and Calorimetry, 147(6), 3437–3445. https://doi.org/10.1007/s10973-021-10943-4
    10. Zeglin, B. (2015). EDS and XRD methods for structural and elemental analysis of mineral composites. Analytical Chemistry Research, 5, 12–19. https://doi.org/10.1016/j.ancr.2015.04.001
    11. KCl, M., & Wulandari, R. (2018). Influence of mineral fillers on the decomposition temperature of ammonium nitrate. Journal of Hazardous Materials, 355, 96–104. https://doi.org/10.1016/j.jhazmat.2018.05.017

Other articles of the issue

Maslak Hanna Sergiivna, Maryaskin Yuri Borisovich, Stanislav Derman, Shevtsova K., Tsokur N. The influence of surfactants on cleaning hard surfaces from oil contaminants.
Download article in PDF1333 views
cc-license
About us Journals Books
Publication ethics Terms of use of services Privacy policy
Copyright 2013-2025 Premier Publishing s.r.o.
Praha 8 - Karlín, Lyčkovo nám. 508/7, PSČ 18600, Czech Republic pub@ppublishing.org